The application relates to the technical field of CO2 capture, in particular to a high-pressure chemical chain coupled
calcium cycle CO2 capture
system and application thereof, and the capture
system comprises a gas-fired power generation unit, a first
waste heat power generation unit and a CO2 separation unit; the CO2 separation unit comprises a first
air compressor, an air reactor, a first
turbine, a
carbonation tower and a calcining furnace. The
calcium cycle is coupled with the chemical chain air reactor in a mode, high-concentration
oxygen in
tail flue gas of
natural gas is used for oxidizing
metal oxygen carriers in the air reactor,
oxygen sources for the calcining furnace are provided, air originally required is replaced, the
combined cycle is driven to work, the problem of
flue gas preheating in the
calcium cycle capture technology of
natural gas flue gas is solved, the remaining oxygen in the
flue gas is fully utilized, the CO2 concentration in the
flue gas entering the
carbonation tower is increased, and the capture
energy consumption is reduced; and since part of the energy is used for driving the
combined cycle, heat exchange loss can be effectively reduced, and the
power output of the capture
system is improved.