The invention belongs to the technical field of concrete preparation, and discloses a high-performance concrete admixture and a preparation method thereof, the high-performance concrete admixture is composed of the following components by mass: 9-15 parts of limestone, 6-10 parts of blast furnace water-quenched slag, 5-6 parts of kaolin, 4-5 parts of desulfurized gypsum, 2-4 parts of alumina, 2-3 parts of a synergist, 1-3 parts of carbon powder, and 1-2 parts of nano silica. The carbon powder is physically treated by utilizing the characteristics of dispersity promotion, defoaming property, rheological property and the like of silicon dioxide, the excellent properties of dispersity promotion, enhancement, defoaming, rheology, sagging prevention and the like are shown in the material, the dispersity of all the components in concrete can be improved, and the viscosity and gas content of a mixture are reduced, so that the working performance and the post-hardening mechanical property of the concrete mixture are improved. The preparation process is simple, raw materials are easy to obtain, and cost is low.