The invention provides a preparation method of
hydroxylamine sulphate and devices used in the preparation method.The method includes the steps of
calcium salt
quenching and
tempering, solution cooling, solution mixing,
mixed solution PH value regulation and solution
hydrolysis.Firstly, the PH value of a
calcium salt solution or turbid liquid is regulated to 0.1-3.5 through acid; then, the
calcium salt solution or the turbid liquid subjected to
quenching and
tempering and a solution containing
nitrite are cooled to 10 DEG C or below respectively; the cooled calcium
salt solution or the turbid liquid is mixed with the solution containing
nitrite at the temperature of 10 DEG C or below; acid is added to the
mixed solution to regulate the PH value of the solution to 0.1-3.5; finally, the solution or the turbid liquid is heated by 0.2-3 hours at a temperature smaller than 150 DEG C to obtain a solution containing
hydroxylamine sulphate.The devices mainly include a calcium salt
quenching and
tempering cooling kettle, a disulfonate preparation reaction kettle and a
hydrolysis reactor.The method is simple in process, mild in reaction condition and high in yield, and by-product resources obtained through
coal-fired
flue gas limestone wet desulphurization can be recycled and converted into
hydroxylamine sulphate high in added value and wide in application range.