The invention belongs to the technical field of extraction, and discloses a combined extraction method of quick-acting
phosphorus suitable for acidic, neutral and
calcareous soil, which comprises the following steps: preparing a composite extraction agent which comprises the following components:
citric acid-
sodium citrate buffer solution, EDTA (
Ethylene Diamine Tetraacetic Acid) disodium salt and
ammonium oxalate; mixing the soil sample with the composite extracting agent; carrying out
solid-liquid separation on a mixture of the soil sample and the composite extracting agent; and carrying out
phosphorus determination on the filtrate obtained by
solid-liquid separation. The
citric acid-
sodium citrate buffer solution is used for maintaining an acidic environment and dissolving iron / aluminum combined
phosphorus; eDTA disodium salt is chelated with
calcium ions, so that refixation of phosphorus in
calcareous soil is prevented; according to the method, the leaching process is simple, the efficiency is high, the universality is high, the
recovery rate is high, the method is suitable for the soil with the pH value of 4.0-8.5, the
recovery rate is larger than or equal to 92%, the leaching cost is low, the method is
environmentally friendly, the composite leaching agent is free of
toxicity and harm and
fluoride and strong acid components, waste is easy to treat, and the method meets the green
chemical standard.