The invention provides a method for synthesizing 2, 5-furandicarboxylic acid through furoic acid and
bicarbonate, and relates to the technical field of chemical synthesizing.The method for synthesizing 2, 5-furandicarboxylic acid through furoic acid and
bicarbonate comprises the following steps that raw materials including furoic acid, basic
metal salt and
bicarbonate are taken and placed in water to react,
drying and smashing are conducted after the reaction is completed, and the furoic acid is obtained; the bicarbonate comprises cesium bicarbonate, and the furoic acid
solid mixture is obtained; taking the furoic acid
solid mixture, placing the furoic acid
solid mixture under the pressure of 0.8-2MPa, heating to 240-320 DEG C, and reacting for more than 15 hours to obtain 2, 5-furandicarboxylate; and dissolving the 2, 5-furandicarboxylic
acid salt in water, and acidifying with
hydrochloric acid to obtain the 2, 5-furandicarboxylic acid. The bicarbonate is heated and decomposed to generate
carbon dioxide, the
carbon dioxide produces a large number of pores in the furoic acid solid mixture, the gas-solid interface surface area is greatly increased, the gas-solid interface reaction is accelerated, the gas-liquid reaction efficiency is improved, and the
energy consumption is reduced.