The present invention discloses an infrared reflection device based on electrical response and a preparation method thereof. Chiral doping agent, chiral monomers, photoinitiator, ultraviolet absorbent are mixed with negative liquid crystal to obtain a liquid crystal mixture, the liquid crystal mixture is disposed between two light transmission substrates to which voltage can be accessed, ultraviolet light irradiates a liquid crystal cell from one side of the first light transmission substrate, the photoinitiator drives the chiral monomers to polymerize a chiral polymer network under the effect of the ultraviolet light, the generated chiral polymer network concentration has a concentration gradient, namely the chiral monomer concentration has a concentration gradient, so that a pitch gradient of a negative liquid crystal helical structure is formed, and a wide bandwidth for reflecting infrared light can be obtained. The chiral polymer network can capture impurity cations in the liquid crystal mixture, when the substrates are powered, the impurity cations drive the chiral polymer network to move, so that the chiral monomer concentration gradient is decreased, the pitch gradient is decreased, and the purpose of changing the bandwidth from wide to narrow is achieved.