The invention discloses a double-hetero-element co-doped
porous carbon material capable of promoting efficient circulation of Fe (III) and Fe (II) of a Fenton
system and a preparation method of the double-hetero-element co-doped
porous carbon material, and relates to the technical field of
water treatment. According to the material, industrial and agricultural wastes such as
lignin, water
hyacinth leaves,
myriophyllum spicatum, camellia seed shells, loofah
sponge,
bagasse and
traditional Chinese medicine residues which are high in carbon content serve as raw materials, a
porous carbon material is formed through
pyrolysis at high temperature by adding pore-forming agents such as
ethylene glycol, and heteroatoms such as
boron,
sulfur,
phosphorus and
nitrogen are introduced for co-
doping. Wherein
boron doping contributes to further improving the graphitization degree and
conductivity of the material, and compared with
phosphorus doping, due to
electronegativity and
atomic radius adaptability of
sulfur and
nitrogen doping, the polarity of the carbon material can be effectively enhanced, electrons in the carbon material can be extracted as active sites, an adsorbed Fe (III) complex is promoted to be reduced to Fe (II), the Fe (III) / Fe (II)
cycle efficiency of a Fenton
system is accelerated, and the performance of the material is improved. The dosage of the Fe (II) medicament is greatly reduced, and meanwhile, the
resource utilization of agricultural wastes can be realized.