The invention relates to an oxygen-rich intelligent temperature-control ladle baking device and a using method thereof. The ladle baking device is provided with a ladle cover, a ladle liner and a burner assembly, a space is reserved between the outer periphery of the ladle liner and the inner wall of a steel ladle, and a gap is further reserved between the periphery of the ladle cover and the edgeof the upper opening of the steel ladle; a plurality of temperature sensors capable of testing the temperature of the outer wall of the ladle liner are arranged on the wall of the ladle liner; the burner assembly is provided with an igniter, a fuel gas pipe, a combustion-supporting gas pipe and a combustion head, the combustion head extends out of the bottom of the ladle liner, the upper end of the burner assembly extends out of the ladle cover, the burner assembly is fixed in the middle of the ladler cover, and a self-control switch of the igniter, a gas inlet of the fuel gas pipe and a gasinlet of the combustion-supporting gas pipe are arranged at the upper end of the burner assembly; and the ladle baking device is further provided with a PLC, and the PLC is in signal and control connection with the temperature sensors and the self-control switch. The ladle baking device has the advantages that the structural design is reasonable, running is safe and reliable, the automation degreeis high, the operation and the use are convenient, the steel ladle is uniformly baked, the baking time is effectively shortened, the baking efficiency is improved, and the pollution to the environment is relatively low.