The invention relates to a preparation method of a terbium-doped calcium sodium phosphate glass ceramic photostimulated luminescence material. The general formula of the material is 25Na2O-23CaO-6P2O5-44B2O3-2ZrO2-xTb4O7, wherein in the formula, x=0.1-1. The method comprises the following steps: sodium carbonate, calcium carbonate, ammonium dihydrogen phosphate, boron oxide, zirconium oxide and terbium oxide are taken as raw materials, mixed sufficiently and pre-sintered, obtained molten glass is quickly poured into a stainless steel mold, calcium sodium phosphate glass is prepared, ground into powder, annealed and pressed into round sheets, the round sheets are placed into a muffle furnace for heat treatment, NaCaPO4 crystals are separated out from the glass, and the terbium-doped calciumsodium phosphate glass ceramic photostimulated luminescence material is obtained. The material has good optical properties, high sensitivity and wide dose response range (0.01-1000 Gy), can be applied to personal dosimeters, environmental dosimeters, medical dosimeters and the like and is an ideal photostimulated luminescence material for detecting radiation dose.