The invention relates to the field of propylene
polymerization, and discloses a preparation method of
polypropylene,
polypropylene and application. The method comprises the following steps: S1, in the presence of a functional external
electron donor and a catalyst
system, carrying out a prepolymerization reaction on propylene to obtain a
prepolymer A; the prepolymerization multiplying power is 1000 to 10000 times; s2, in the presence of a first molecular weight
regulator, a first external
electron donor and the
prepolymer A, performing a first
polymerization reaction on propylene to obtain a
polymer B; s3, in the presence of a second molecular weight
regulator, a second external
electron donor and a
polymer B, carrying out propylene second
polymerization reaction to obtain
polypropylene. According to the method, the prepolymerization reaction is combined with the polymerization reaction of two stages, the functional external
electron donor is introduced in the prepolymerization process, and the specific first external
electron donor and the specific second external
electron donor are subsequently matched, so that the prepared polypropylene has good processability and
heat resistance.