The invention discloses a Chinese herb shampoo and a preparation process thereof. The traditional shampoo is prepared from, by weight, pure water, a surfactant, mixtures of Chinese herb extracts, a conditioner for hair, a humectant, a pH modifier, an emulgator, a thickener and other components; the surfactant at least includes five of laurinol polyether sodium sulfovinate, cocoamidopropyl betaine,amphoteric disodium cocoyl oxalate, cocamide DEA, sodium lauroyl sarcosine and potassium cocoyl glycinate; the mixtures of the Chinese herb extracts include chrysanthemum extracts, garden balsam stemextracts, safflower extracts, cacumen biotae extracts, polygonum multiflorum extracts and angelica sinensis extracts; the conditioner for the hair comprises poly-quaternary ammonium salt-52, PPG-3 octyl ether, guar hydroxypropyltrimonium chloride and poly-quaternary ammonium salt-10; the other components at least include one of preservative and aromatic. The Chinese herb shampoo has excellent effects of hair fixation, itch relief, dandruff and oil removal, oil control, prevention and the like.