The present invention provides a high dielectric microwave dielectric ceramic material, the general chemical formula of the material is (Ca0.35Li0.25Nd0.35)(Ti1-xDx)O3, wherein 0.01≤x≤0.05, the composition of D is VW, and V represents the valence state Higher than tetravalent Ta, W represents a single or multiple elements whose valence is lower than tetravalent and the average ionic radius is close to Ti4+, V and W can be substituted simultaneously or separately; the present invention also provides a high dielectric microwave dielectric ceramic The preparation method of the material comprises the steps of: batching, ball milling, drying and sieving, pre-calcination, granulation, compression molding, and sintering; the material prepared by the invention has a high dielectric constant and a relatively high Q×f value, and can be adjusted Frequency temperature coefficient. The formula does not contain volatile toxic metals such as Pb and Cd, and has stable performance, which can meet the application requirements of modern microwave devices. The raw materials are abundantly supplied in China and the price is relatively low, which makes it possible to reduce the cost of high-performance microwave ceramics.