The invention discloses an internally-added non-
silicon release master batch, a preparation method and a release film with nanoscale roughness, preparation raw materials comprise PET resin I, a non-
silicon release agent composition and an
antioxidant, and the non-
silicon release agent composition comprises
polyester wax and oxidized polyethlene
wax. According to the invention,
polyester wax and oxidized polyethlene wax are compounded, and a release functional phase which is uniformly dispersed in nanoscale and has a stable interface is constructed in a PET matrix through a unique molecular synergistic effect and a
processing technology matched with the
polyester wax and the oxidized polyethlene wax, so that the fundamental contradiction that the surface of an internally added release film is rough and the release function is difficult to consider at the same time is solved; and meanwhile, silicon migration
pollution is fundamentally eradicated, the process is simplified by utilizing an internal addition process, and recycling is facilitated.