The invention discloses a manufacturing method of a coiled bipolar membrane. The method includes: 1) unreeling a coiled sulfonated
polystyrene-
polyethylene cation exchange dry film reel and a
polyolefin film reel respectively, then performing overlapping, then conducting hot-pressing by a four-roll
hot press, cooling by a five-roll cooling unit and winding by a winder in order, thus obtaining a single-side coated
polyolefin coated positive membrane roll; 2) loosening the
polyolefin coated positive membrane roll, spraying a polymeric
monomer solution containing a
functional monomer, a crosslinking agent and an initiator to the
coating surface, carrying out overlapping with a
polyester protective film alternately, and performing compaction, then performing winding, placing the whole object in a constant temperature oven and conducting heating to initiate
polymerization, and stripping the
polyester protective film to obtain an absorption positive membrane roll with single side containing a functional
polymer; and 3) selecting a
polypropylene isolation net and the absorption positive membrane roll obtained in step 2) to conduct loose alternate winding, carrying out
amination reaction in a mixed water solution of
dimethylamine and
trimethylamine, performing washing, then stripping the
polypropylene isolation net, and winding a wet film individually, thus obtaining the coiled bipolar membrane.