The invention discloses an environment-friendly
flame-retardant poly (aromatic ester-
ether)-based biodegradable material
polyester and a preparation method thereof. According to the method, 3-allyl-4-
hydroxybenzoate, cyclohexyl-1, 4-dimethyl
alcohol monovinyl
ether and a specific
halogen-free
flame retardant allyl
phosphate diester are taken as reaction monomers, and the environment-friendly
flame-retardant poly (aromatic ester-
ether) dihydric
alcohol copolymer is synthesized through
emulsion polymerization; and then, by taking the
copolymer as a precursor, carrying out esterification and polycondensation on the
copolymer, organic
dibasic acid, a polyfunctional cross-linking agent and a stabilizer under the action of a catalyst to prepare the environment-friendly flame-retardant poly (aromatic ester-ether)-based biodegradable material
polyester. According to the invention, the molecular design realizes the synergistic interaction of group enrichment effect and
rigid structure effect for the first time, and breaks through the
bottleneck of poor flame retardance of the traditional biodegradable material
polyester; meanwhile, emission of corrosive gases such as dioxin and
hydrogen halide during
combustion is avoided, and the material is endowed with efficient biodegradability and green flame retardant property.