The invention discloses a start-up system of a laser methane sensor with a peak shifting opening function. The start-up system comprises a plurality of laser methane sensors, a power supply bus, a plurality of power supply modules, a plurality of switches K0 and random number modules, the number of the laser methane sensors, the power supply modules, the switches K0 and the random number modules is the same, one end of the power supply bus is connected with a power supply, the other end is connected with all switches K0 in parallel, each switch K0 is connected with one power supply module, onepower supply module is connected with one laser methane sensor, one random number module is connected between each laser methane sensor and the switch K0, the problem that the sensors on the bus cannot be normally started up since the plurality of sensors are connected onto one power supply and when the sensors are started up simultaneously, and the instantaneous start-up current is greater underthe condition that an intrinsic safety power supply is used in a coal mine and the power supply distance is long and when a plurality of sensors which are hung on the same power supply bus are started up simultaneously can be solved.