The invention discloses a method for regulating and enhancing
ultraviolet fluorescence of
rare earth up-conversion nanocrystals through a
local structure and a method for measuring the
local structure, and belongs to the field of
rare earth luminescent
nanomaterials. According to the method, in the process of synthesizing the LiREF4: coated LiREF4 core-shell structure, the stoichiometric ratio of LiOH and NH4F in a core layer and / or the use amount of
lithium trifluoroacetate in a shell layer are precisely regulated and controlled, and the localized
crystal field environment around activated ions is changed, so that the selective regulation and control on the
luminescence transition path of the activated ions are realized, and the
emission intensity of multiphoton
ultraviolet up-conversion
luminescence is improved. According to the method, the high-order multi-
photon up-conversion process of
rare earth ions can be remarkably enhanced, meanwhile, low-order emission is inhibited, the
luminescence selectivity of an up-conversion nano material is improved, emission light with the corresponding
wavelength can be synthesized from the same matrix material according to the requirements of synthesizers, and the method can be suitable for various rare earth active ions and matrix materials and has a wide application prospect. The method has application potential in the fields of nano
photonics and
biomedicine.