An optical waveguide-forming composition: 100 parts by mass of a reactive silicone compound (a) composed of a polycondensate of a diarylsilicic acid compound A of Formula [1]
Ar1 and Ar2 are a phenyl, naphthyl or a biphenyl group optionally substituted, and an alkoxy silicon compound B of Formula [2]
Ar3—Si(OR1)aR23-a [2]
Ar3 is a phenyl, naphthyl or biphenyl group having at least one group having a polymerizable double bond, R1 is methyl or ethyl group, R2 is methyl, ethyl, or vinylphenyl group, and a is 2 or 3, and 1 part by mass to 200 parts by mass of a di(meth)acrylate compound (b) of Formula [3].
R3 and R4 are a hydrogen atom or methyl group, R5 is a hydrogen atom, methyl group, or ethyl group, L1 and L2 are an alkylene group, and m and n are 0 or a positive integer, wherein m+n is 0 to 20.