The invention provides a lithium ion battery positive pole piece, which comprises a positive current collector, a conductive coating layer and an active slurry layer, wherein the conductive coating layer and the active slurry layer are sequentially coated on the positive current collector, and the active slurry layer comprises, by mass, 95% of a LiFePO4 active substance, 2.8% of a conductive agent and 2.2% of a binder; the conductive coating layer comprises the following components in percentage by mass: 10% of a conductive agent, 2% of a binder, 1% of ethanol, 1% of acetone and 86% of deionized water; the binder is polyvinylidene fluoride, the conductive agent is conductive carbon black, and the positive active substance is LiFePO4. The preparation method is simple, the conductivity of the pole piece can be effectively improved, the lithium ion transfer impedance in the battery is obviously reduced, the direct-current internal resistance of the battery is obviously reduced, and the cycling stability of the battery can be improved.