The invention relates to a positive pole piece, a preparation method thereof and a lithium ion battery. The preparation method of the positive pole piece comprises the following steps: step 1, premixing a ternary material with lithium manganate to prepare a cathode active material; step 2, mixing the cathode active material with a binder, a conductive agent and an organic solvent, and pulping the mixture to obtain a stable slurry; step 3, adding a certain amount of lithium carbonate into the slurry; step 4, coating an aluminum foil tape with the slurry, drying, rolling, and slicing, so as to obtain the positive pole piece. The positive pole piece prepared by adopting the preparation method provided by the invention improves the high temperature performance and the cycling stability of lithium ion batteries, greatly reduces the cost of materials, shortens the fusion time of the cathode material, the binder and the conductive agent and improves the production efficiency; besides, as a defined amount of lithium carbonate is added into the slurry, electrolyte decomposition in the cyclic process of batteries is effectively inhibited, and at the same time the solid electrolyte interphase (SEI) film is endowed with better viscoelasticity, the intercalation of lithium ions is facilitated, and both the electrochemical performance and the safety performance of batteries are further improved.