The invention discloses a large-scale energy storage direct current high-voltage control system and control method therefor. The large-scale energy storage direct current high-voltage control system comprises a large-scale energy storage battery, a load/charger, a fuse protector, a dual-channel high-voltage direct current circuit breaker, a pre-charging relay, a general positive relay, a general negative relay, a low-voltage power supply, an emergency stop switch, a battery management system, a Hall sensor, a red indicating lamp, a green indicating lamp and a gold resistor. The large-scale energy storage direct current high-voltage control system is more strict in safety control, and through fusion protection and multiple safety protection of the direct current high-voltage circuit breaker, the general positive relay, the general negative relay, the emergency stop switch and the like, safety of the large-scale energy storage system can be ensured; and meanwhile, the control method forthe large-scale energy storage direct current high-voltage control system can be realized easily, and through modular setting, the generated codes can better satisfy logic control without causing faults.