The invention discloses a monitoring system of multi-component gas pollutants in air of a chemical industrial park. The monitoring system comprises a PID sensor, an electrochemical sensor, a catalytic combustion sensor, a geographic information determination apparatus a signal conversion apparatus, a memory, a controller, an acousto-optic alarm apparatus, wherein the PID sensor, the electrochemical sensor, and the catalytic combustion sensor commonly form a part for frontal acquisition and detection of the pollutants of the monitoring system, and the part of the monitoring system is used for pollutant kind determination and parameter coupling analysis. The PID sensor comprises a gas acquisition device, a filtering device, and a photo-ionization sensor detection device; the electrochemical sensor comprises a gas acquisition device, a dedusting device, and an electrochemical sensor detector; and the catalytic combustion sensor detector comprises a gas acquisition device, a catalytic combustion sensor detector, and an outrange and reversed polarity protection device. The monitoring system also comprises the controller for statistics and analysis of detection results, and the acousto-optic alarm apparatus for alarm when the gas concentration in the pollutants exceeds a standard.