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A separation and recovery device for thiophene-containing BT oil includes a BT oil thiophene removal system, a first distillation column, and a second distillation column. The inlet of the BT oil thiophene removal system is connected to a BT oil source, and the outlet is fed to the first distillation column via a first pipeline. The outlet of the condenser at the top of the first distillation column forms a first benzene outlet, and a first reflux pipeline is provided connected to the reflux port of the first distillation column. The bottom of the first distillation column is fed to the second distillation column via a second pipeline. The top of the second distillation column is connected to the inlet of the reboiler heat exchange medium channel at the bottom of the first distillation column via a third pipeline. The outlet of the reboiler heat exchange medium channel at the bottom of the first distillation column forms a second benzene outlet, and a second reflux pipeline is provided connected to the reflux port of the second distillation column. This invention has a simple structure, is easy to operate, and can effectively separate and recover benzene and toluene from BT oil with high purity. It also effectively reduces the heat load of separating benzene and toluene, and can handle high-concentration thiophene petroleum benzene.