The present invention is DL-18 multiple-element aluminium spectrum standard sample and its preparation. The sample contains in pure aluminium 18 kinds of elements or partial of the elements, including Si, Fe, Cu, Mg, Mn, Ni, Zn, Ti, V, Pb, Sn, Ga, Cd, CE, CA, SB, Na and B. The addition method of its 10 kinds of elements is provided. The present invention expands the analysis range to aluminium material for meeting the need of developing new aluminium material.