The invention provides a preparation method of a printed circuit board. The method includes the following steps of: S1, copper foil arrangement: copper foil is arranged on a carrier in a manner that the copper foil is aligned with the carrier, and the copper foil and the carrier are composited; S2, laser cutting: laser cutting is performed on the pattern of the circuit diagram of a circuit board;S3, selective peeling: an aluminum substrate is coated with photoresist, and a mask with a circuit diagram is arranged on the aluminum substrate, and the aluminum substrate is selectively exposed according to the pattern of the circuit diagram, so that the non-circuit portion of the circuit diagram loses viscosity; and S4, printed circuit board preparation: the copper foil arranged on the carrieris aligned with the aluminum substrate, so that the circuit diagrams of the copper foil and the aluminum substrate are completely overlapped with each other, and the copper foil of a circuit portion is completely bonded to the aluminum substrate, and the copper foil of a non-circuit portion is peeled off. According to the preparation method of the invention, the circuit board is inscribed by a laser cutting method, so that chemical etching can be avoided in a production process; and waste copper can be directly recycled, and therefore, a great environmental protection value can be realized with cost reduced. With the method adopted, a new idea is provided for the production of copper foil for circuit board.