The invention discloses a multifunctional intelligent distillation instrument. The distillation instrument comprises a shell, a support, heating devices and a cooling device, wherein the heating devices are a plurality of relatively independent heating units, and each heating unit comprises a heating jacket, a heating bar, a heating bowl and a distillation bottle; the heating bowl is arranged in a heating box, the open end of the upper part of the heating bowl is provided with a stove port, and the distillation bottle is arranged in the stove port; the heating jacket is fixed on the periphery of the heating bowl; and the distillation instrument is also provided with a measurement and control device, a temperature sensor is fixed on the top of each heating bowl and connected with a control circuit board through a signal wire and transfers heating temperature to a control chip on the control circuit board, and a liquid level sensor is fixed on a console and senses the liquid level state in a volumetric flask through an optical fiber. The instrument can be widely applied to distillation treatment of projects of volatile phenol, cyanide, ammonia nitrogen, Kjeldahl nitrogen, water in oil and the like in various chemical laboratories requiring distillation treatment in environment friendliness, disease control, water supply and drainage, colleges, research institutions, industrial enterprises and the like.