The invention discloses a 
microemulsion liquid membrane chemical applicable to treating heavy 
metal, 
ammonia nitrogen and radioactive 
wastewater. The 
microemulsion liquid membrane chemical comprises a membrane phase and an internal water phase, the membrane phase is mainly composed of an 
organic solvent, a support film agent, a carrier substance and water, and the volume ratio between the membrane phase and the internal water phase is 1:(0.5-2). A method for treating waste water by the 
microemulsion liquid membrane chemical includes the following steps of firstly using the membrane phase and the internal water phase to prepare a W / O type 
emulsion, then adding the W / O type 
emulsion in an extract 
tower to perform a waste 
water treatment, transferring a mixed liquor obtained from the treatment to a liquid separating 
tower to perform still standing and layering, subjecting layered 
oil phase to a subsequent 
high pressure electrostatic 
emulsion breaking, releasing pollutants from an emulsion dispersed phase to form an organic phase and a 
pollutant containing solution, recycling the organic phase, and subjecting the 
pollutant containing solution to a 
recovery processing. The microemulsion liquid membrane chemical and the treating method thereof applicable to treating heavy 
metal, 
ammonia nitrogen and radioactive 
wastewater have the advantages that the equipment investment is small, the 
land occupation is small, 
processing capabilities are high, the cost is low, the secondary 
pollution is absent, the fluidized 
processing and all-way 
automatic control can be achieved, and the like.