The invention discloses a test method for the residual
phthalate ester, including the steps that after a
solid sample is decomposed into blocks which are immersed in the dummy
body fluid, the transferring amount of the
phthalate ester in the
solid sample under the condition with the dummy
body fluid can be obtained through the auxiliary lixiviation by water bath
ultrasound, the purification and the enrichment of
solid extraction columellas filled with multi-walled carbon nano-tubes, and the measurement by a gas
mass spectroscopy; and meanwhile, after the solid sample is decomposed into blocks, the total content of the
phthalate ester in the solid sample can be obtained through the extraction by an accelerating
solvent extraction method, the purification and the enrichment of small solid extraction columns filled with multi-walled carbon nano-tubes, and the measurement by a gas
mass spectroscopy. The invention has the advantages of less dosage of
organic solvent, rapid extraction speed, less
impurity interference, high sample
recovery ratio, and the like. In addition, prefilled small solid extraction columns are made from the multi-walled carbon nano-tubes, thereby the enrichment effect of the phthalate ester in the dummy
body fluid extract of samples to be tested can be greatly improved, and a phthalate ester
hazard evaluation system can be better perfected according to the difference of the total residual quantity and the dissolved quantityof phthalate ester in the solid sample.