The invention discloses a test method for the residual phthalate ester, including the steps that after a solid sample is decomposed into blocks which are immersed in the dummy body fluid, the transferring amount of the phthalate ester in the solid sample under the condition with the dummy body fluid can be obtained through the auxiliary lixiviation by water bath ultrasound, the purification and the enrichment of solid extraction columellas filled with multi-walled carbon nano-tubes, and the measurement by a gas mass spectroscopy; and meanwhile, after the solid sample is decomposed into blocks, the total content of the phthalate ester in the solid sample can be obtained through the extraction by an accelerating solvent extraction method, the purification and the enrichment of small solid extraction columns filled with multi-walled carbon nano-tubes, and the measurement by a gas mass spectroscopy. The invention has the advantages of less dosage of organic solvent, rapid extraction speed, less impurity interference, high sample recovery ratio, and the like. In addition, prefilled small solid extraction columns are made from the multi-walled carbon nano-tubes, thereby the enrichment effect of the phthalate ester in the dummy body fluid extract of samples to be tested can be greatly improved, and a phthalate ester hazard evaluation system can be better perfected according to the difference of the total residual quantity and the dissolved quantityof phthalate ester in the solid sample.