The invention discloses a trifluoromethylpropenyl compound, a preparation method and application thereof. The present invention directly uses allyl alcohol as raw material, selects CF 3 SO 2 Na is used as a trifluoromethylation reagent, using a metal-free and inexpensive photoredox catalyst, under the catalysis of an organic photoredox agent, the by-product SO is generated in situ 2 is repurposed to activate the C‑OH bond, allowing the reaction to occur in an environmentally friendly manner under mild conditions. The allyl alcohol used in the preparation method of the present invention is the MoritA-Baylis-Hillman alcohol allyl alcohol raw material with simple synthesis and high conversion rate, a wide range of applicable substrates, and low preparation cost; in addition, the preparation method of the present invention has simple steps, It has the characteristics of convenient operation, environmental protection, excellent stereoselectivity, and tolerance to broad-spectrum functional groups; the trifluoromethylpropenyl compound of the present invention is the preparation of related CF 3 Universal precursors of molecules with potential drug activity and biological activity can be widely used in biologically and pharmaceutically active molecules.