The invention discloses a wearable exoskeleton upper-limb rehabilitation robot. The wearable exoskeleton upper-limb rehabilitation robot comprises an arm adjustment component, a shoulder joint flexion and extension component, a shoulder joint folding and unfolding component, an upper-limb rotational motion component, an elbow joint flexion and extension component,, a front-arm rotational motion component, a wrist joint flexion and extension component and a frame motor component. The arm adjustment component is fixed to the frame motor component. The arm adjustment component, the shoulder joint flexion and extension component, the shoulder joint folding and unfolding component, the upper-arm rotational motion component, the elbow joint flexion and extension component, the front-arm rotational motion component and the wrist joint flexion and extension component are connected in sequence. The wearable exoskeleton upper-limb rehabilitation robot has the advantages that six-freedom-degree motion of flexion and extension as well as inward folding and outward unfolding of shoulder joints, internal and external rotation of upper arms, flexion and extension of elbow joints, internal and external rotation of front arms and flexion and extension of wrist joints can be achieved, and one-freedom-degree motion of arm adjustment can be also achieved; all the joints of the upper-limb rehabilitation robot are driven indirectly, the weight of robot arms is reduced, weight loading capability of the robot arms is improved, mechanical structure is simplified, and flexibility of the robot is improved.