An off-resonance photoacoustic spectrometric detection and analysis device consists of a photoacoustic spectrometric module (8). The photoacoustic spectrometric module (8) comprises a light source module (2-1), a photoacoustic signal generation module (2-2), an optical power measurement module (2-3) and a fault diagnostic analysis module (2-4). Optical signals generated by an infrared incoherence light source in the light source module (2-1) are focused by an ellipsoidal reflector to form a focused light beam, the focused light beam is modulated into light of specific frequency and wavelength by chopping blades of an optical chopper and optical filters and then transmitted to the photoacoustic signal generation module (2-2), and the fault diagnostic analysis module (2-4) calculates each gas concentration according to to-be-tested gas photoacoustic signals generated by irradiation, diagnoses faults and alarms. The off-resonance photoacoustic spectrometric detection and analysis device can be used for quantitative detection of gases such as SF6, CF4, SO2F2, SOF2, SO2, SF4 and H2O and is applicable to onsite online monitoring.