The invention provides a process for recycling products from mother liquid containing
ammonium chloride,
sodium chloride,
ammonium hydrogen carbonate and
sodium hydrogen carbonate through a thermal method. The process comprises a method for recycling gas generated after deaminizing the mother liquid. The method for recycling the gas generated after deaminizing the mother liquid comnprises the following steps: preheating the mother liquid, then feeding the mother liquid into an
ammonia still for deaminizing, feeding
carbon dioxide and
ammonia gas generated after deaminizing into an
ammonia absorption
tower for generating carbon-containing ammonia water, adding
carbon dioxide into the carbon-containing ammonia water, enabling
carbon dioxide in the carbon-containing ammonia water to be excessive and generate
ammonium hydrogen carbonate. The process also comprises a method for recycling the deaminized mother liquid and obtaining
ammonium chloride and
sodium chloride. The method for recycling the deaminized mother liquid and obtaining
ammonium chloride and sodium chloride comprises the following steps: carrying out five-effect cross-flow
evaporation to obtain sodium chloride, carrying out four-effect
flash evaporation and
crystallization to obtain
ammonium chloride, feeding salt thickener overflowing liquid and salt centrifugal
machine post-throwing liquid into a V-effect
evaporation tank and enabling the salt thickener overflowing liquid and the salt centrifugal
machine post-throwing liquid to participate in circulation again; feeding ammonium thickener overflowing liquid and ammonium centrifugal
machine post-throwing liquid into an IV-effect
flash evaporation and
crystallization tank by using a pump, and enabling the ammonium thickener overflowing liquid and the ammonium centrifugal machine post-throwing liquid to participate in production circulation again. The process is capable of simultaneously recycling to obtain ammonium chloride and sodium chloride; meanwhile, the recycling rate is extremely high; the process is also capable of effectively increasing the heat
utilization rate.