The present invention is one kind of composite organic-inorganic material film as immobilized cell carrier. The composite organic-inorganic material film is prepared through adding alumina precursor, such as boehmite, pseudo boehmite, mesoporous molecular sieve MCM-41, etc to polymer material, such as foamed polyurethane, sodium alginate, PVA, etc. for modification. It is superior to traditional immobilized cell carrier material, and has unique pore canal structure for microbe cell to habitat and to propagate. It has coating and adsorbing amount up to 3-6 billion/ml and free fermenting cell up to 0.08-0.16 billion/ml, and may be used for immobilized cell, especially alcohol fermentation to shorten fermentation period and raise alcohol yield. It has the features of high permeability, high mechanical strength, high chemical stability and capacity of being reused, and is one kind of high efficiency immobilized cell carrier.