The application discloses a method for preparing ultra-
high resistivity silicon substrate by a
Czochralski method, and the process flow of the method is as follows: preparing a
silicon single crystal by the
Czochralski method, rolling and
grinding the
single crystal rod, multi-
wire cutting, edge chamfering, double-side
grinding, chemical
etching, heat treatment and chemical mechanical
polishing; wherein, in the process of preparing the
silicon single crystal by the
Czochralski method, a horizontal superconducting
magnetic field is used in the
single crystal growth process, the
magnetic field strength is 1000-5000 Gauss, meanwhile, specific
crystal rotation speed and
crucible rotation speed are matched, the
crystal rotation speed is 1-12 rpm, and the
crucible rotation speed is 0.1-2 rpm; the heat treatment process is POLY+LTO thin film growth or high-temperature annealing. The method is suitable for preparing P-type silicon substrate with a
diameter of 8 inches or above, a resistivity of 3000
ohm*cm or above and
oxygen content of 5 ppma or below. The prepared single
crystal has an
oxygen content of less than 5 ppma, a resistivity of more than 3000
ohm*cm after annealing, an
oxygen content uniformity of less than 10%, and a resistivity uniformity of less than 5%.