The invention discloses a method for testing the content of easily-volatile matters in explosive, and provides a device improved based on a microcalorimeter correspondingly, wherein the device is formed by arranging a presser sensor used for measuring the real-time pressure in a sample cell on the sample cell of the microcalorimeter and arranging a reading device, a searching device and a comparing device on a control system of the microcalorimeter. In testing, the explosive is put into the sample cell firstly, and after vacuumization is carried out, the device provided by the invention is started, parameters including the start temperature, the temperature rise amplitude, the reaction judgment sensitivity, the constant temperature time, the waiting time, the reaction termination conditions and the like of the microcalorimeter are set, the pressure change and the temperature rise rate change in the sample cell are recorded, and then the content of the volatile matters is obtained by an ideal gas state equation. According to the invention, by analyzing the relationship between the gas discharge quantity and the heat flux change, the content of the easily-volatile matters in the explosive can be effectively tested.