The invention belongs to the technical field of ceramic materials, and in particular relates to a method for preparing a large-aperture three-dimensional network SiC ceramic material. The present invention is to mix SiC powder and B4C powder, add ammonia water, sugar, acrylamide, N, N-methylenebisacrylamide and water ball mill and mix evenly to form SiC mixed slurry, and add surface activity to SiC mixed slurry Agent, foaming agent hydrogen peroxide and binder, stir well and add initiator gel to foam to obtain foam gel, under the protection of inert atmosphere, heat-preserve and sinter the foam gel at 1950-2040°C for 0.5-1h to obtain Large-aperture three-dimensional network SiC ceramic material. The invention can prepare macroporous three-dimensional network silicon carbide. By controlling the concentration and addition amount of polyvinyl alcohol, the pore size can be controlled. At the same time, the addition amount of hydrogen peroxide aqueous solution can control the porosity and pore size, and the use of surfactant is effective. Improving the connectivity of large pores is simple, reliable, does not require large fixed investment, and has good application prospects.