57results about How to "Excellent surface curing" patented technology

The invention relates to the field of coatings and particularly discloses an ultraviolet-thermal curable coating. The ultraviolet-thermal curable coating is prepared from the following raw materials in percentage by weight: 17.5-25% of aliphatic polyurethane acrylate, 5-12.5% of hydroxy acrylic resin, 7-17.5% of reactive diluent, 1.8-4.5% of photoinitiator, 0.2-0.6% of leveling agent, 0.05-0.2% of defoamer, 40-60% of inert solvent and 2-5% of aliphatic polyurethane acrylate containing an NCO group. The ultraviolet-thermal curable coating provided by the invention has the advantages that 1. the curing depth is not limited by the light transmission capacity; 2. curing is easy to perform in a colored system; and 3. curing can be performed in a shadow zone at which ultraviolet rays can not arrive.

An object of the present invention is to provide an artificial nail composition having improved curability. Another object of the present invention is to provide an artificial nail composition which causes less yellowing and has excellent internal curability.The artificial nail composition comprises:a component (a): a compound having at least one radical polymerizable unsaturated double bond in the molecule, and a component (b): a photopolymerization initiator selected from (i) an acylphosphine oxide-type photopolymerization initiator and (ii) a mixture of an acylphosphine oxide-type photopolymerization initiator and an α-hydroxyalkylphenone-type photopolymerization initiator, wherein the amount of the component (b) is 0.05 to 4.00 parts by weight with respect to 100 parts by weight of the component (a). It is preferred that the acylphosphine oxide-type photopolymerization initiator is monoacylphosphine oxide and / or bisacylphosphine oxide, and the α-hydroxyalkylphenone type polymerization initiator is 1-hydroxy-cyclohexyl-phenyl-ketone or 2-hydroxy-2-methyl-1-phenyl-propan-1-one.

The present invention discloses a photocurable composition for forming an anti-fogging coating, comprising: (A) a urethane compound containing at least two (meth)acryloyl groups and a polyoxyalkylene chain in a molecule thereof, (B) a compound having at least two (meth)acryloyl groups and at least two hydroxyl groups in a molecule thereof, obtained by reacting at least two components consisting of an epoxy compound and (meth)acrylic acid, (C) a compound having an ethylenic unsaturated group other than the components (A) and (B), and (D) a photopolymerization initiator, and also discloses a method for forming an anti-fogging coating using this composition.

Disclosed is a photocurable / thermosetting resin composition developable with a diluted alkali solution, which resin composition is characterized by containing (A) an ethylenically unsaturated group-containing carboxylic acid-containing resin, (B) a sensitizer containing a coumarin backbone represented by the formula (I) below and having a maximum absorption wavelength at 360-410 nm, (C) a photopolymerization initiator, (D) a compound having two or more ethylenically unsaturated groups in a molecule, (E) a filler and (F) a thermosetting component.

A photocurable composition for a nail or artificial nail which can form a cured product exhibiting excellent durability (adhesion maintainability to nails). In addition, the present invention provides a photocurable composition for a nail or artificial nail which emits a weaker odor, generates less heat at the time of curing, and can form a cured product exhibiting excellent surface curability. In addition, the present invention provides a photocurable composition for nail or artificial nail which can form a cured product having an excellent shear adhesive force. The photocurable composition for nail or artificial nail according to the present invention contains the following components (A) to (D): component (A): a urethane-modified (meth)acrylic oligomer; component (B): a (meth)acrylamide monomer; component (C): a (meth)acrylic monomer having an acidic group; and component (D): a photoinitiator.

A photocurable and thermosetting resin composition developable with a dilute alkaline solution containing: (A) an ethylenic unsaturated group-containing and carboxylic acid-containing resin, (B) a coumarin skeleton-containing sensitizer having a maximum absorption wavelength of 360 to 410 nm, as represented by the following Formula (I):(C) a photopolymerization initiator, (D) a compound having two or more ethylenic unsaturated groups in the molecule, (E) a filler, and (F) a thermosetting component.

The purpose of the present invention is to provide a hardenable resin composition which can have superior surface hardenable property by irradiation with an active energy beam of 350 to 420 nm in wavelength. The hardenable resin composition contains: a compound (A) having at least one unsaturated double bond; a compound (B) having an oxime ester group; and a benzophenone compound (C ) containing sulfur atoms and hardened with an active energy beam of 350 to 420 nm in wavelength.

The invention discloses an ultraviolet) / moisture / thermal triple curing organic silicone adhesive which comprises the following components in parts by weight: 100 parts of (methyl) acroloyl-oxy alkyl urea alkoxy silicon terminated dimethyl siloxane, 0.5-5 parts of a photoinitiator, 0.5-5 parts of a moisture curing catalyst, 0.5-5 parts of a free radical photoinitiator and 1.0-40 parts of fumed silica. The organic silicone adhesive can be applied to adhesion or encapsulation, a part exposed in the air can be rapidly cured through ultraviolet rays, a shadow area or a lighttight part can be curedthrough moisture or heating, the production efficiency can be greatly improved, and the problem that organic silicon is long in curing time and low in curing efficiency in mere moisture curing or thermal curing can be avoided.

The present invention discloses a photocurable composition that is combinable with a thermally curable clearcoat composition to form a dual curable composition that is useful for forming clearcoats with improved sag resistance. The photocurable composition of the invention includes at least one photocurable oligomer; a first photoinitiator that absorbs light in a first spectral region such that curing of the photocurable composition preferentially occurs near the surface of the of the coating; and a second photoinitiator that absorbs light in a second spectral region such that curing of the photocurable composition occurs throughout the coating. The present invention also provides a method of coating a substrate with a dual curable composition.

The invention provides a photo / thermal initiation fast curing adhesive which comprises the following components by mass: 40-70 parts of one or more epoxy resin matrixes, 20-40 parts of a latent thermal initiation curing agent, 0.5-5 parts of one or more photo initiation curing agents, 0.1-2.5 parts of one or more photosensitizers, 15-35 parts of one or more flexibilizers, and 20-40 parts of one or more fillers. A preparation method of the photo / thermal initiation fast curing adhesive comprises the following steps: at first, under the action of ultraviolet light, the photo initiation curing agents are used for initiating part of epoxy resin to perform a curing reaction, under the action of heat released during the curing reaction and an external heat source, the temperature of the cured part reaches the latent imidazole initiation reaction temperature of 70-90 DEG C, a latent imidazole complex is activated, epoxy resin is initiated to be quickly cured within 3 min, the automatic, high-quality and fast-cementing connection requirements of a car composite material are met, and the technical problems such as mismatch between the traditional adhesive curing initiation condition and the connection working condition of the car composite material are solved.

The invention relates to a high-hardness and high-gloss ultraviolet light polymerization coating used for PVC floor tiles. The coating is prepared and characterized by comprising the raw materials in percentage by mass: 30-45% of a mixture of aliphatic polyurethane diacrylate and photosensitive phenolic aldehyde epoxy acrylate, 3-5% of graphitized nano carbon fiber, 5-12% of an initiating agent, 1-3% of a surface assisting agent, 5-10% of a cosolvent, 10-20% of a reactive diluent, 1-2% of a polyacrylate or organosilicone leveling agent, 10-30% of an inert solvent and 0-2% of pigment. The coating provided by the invention has the performances of high hardness, high tenacity and high gloss, and besides, is further provided with higher salt fog resistance, ageing resistance, wearing resistance, scratch resisting capability, adhesive force, and cold and hot impact capacity.

The invention provides a fluoro-containing fluorene oxime ester photoinitiator, a photocurable composition containing the same, and an application thereof. The photoinitiator has a structure representby that general formula (I). In the fluoro-containing fluorene oxime ester photoinitiator provided in the present application, by introducing a polymerizable group at the 9-position of the fluorene structure, the formed photoinitiator can be polymerized with a substrate, and thus the photoinitiator has the advantage of being difficult to migrate. At that same time, the photoinitiator provide in the present application also has the advantage of high initiation efficiency due to the introduction of fluorine-containing groups. In addition, the special structure of the photoinitiator also has theadvantages of good surface drying performance, good surface curing effect and so on. On this basis, the photoinitiator has the advantages of not easy migration, high initiation efficiency, good surface drying performance and good surface curing effect, and has a broad application prospect.

The present invention discloses a photocurable composition for forming an anti-fogging coating, comprising: (A) a urethane compound containing at least two (meth)acryloyl groups and a polyoxyalkylene chain in a molecule thereof, (B) a compound having at least two (meth)acryloyl groups and at least two hydroxyl groups in a molecule thereof, obtained by reacting at least two components consisting of an epoxy compound and (meth)acrylic acid, (C) a compound having an ethylenic unsaturated group other than the components (A) and (B), and (D) a photopolymerization initiator, and also discloses a method for forming an anti-fogging coating using this composition.

The invention relates to the field of the coatings and in particular relates to an ultraviolet curable antifouling flame-retardant coating for a plastic circuit board. The ultraviolet curable antifouling flame-retardant coating for the plastic circuit board, namely an ultraviolet curable antibacterial coating for a metal building material, is characterized by being prepared from the following raw materials in percentage by weight: 30%-45% of mixed UV resin of aliphatic polyurethane diacrylate and bisphenol A epoxy diacrylate, 3%-5% of graphitized carbon nanofibers, 5%-12% of an initiator, 1%-3% of surface auxiliaries, 5%-10% of a cosolvent, 10%-20% of a reactive diluent, 1%-2% of a nano-silver antimicrobial agent and 10-30% of an inert solvent. The ultraviolet curable antifouling flame-retardant coating for the plastic circuit board has the antifouling and flame-retardant capability without affecting the intrinsic performance indexes of the coating.

The invention relates to an aromatic sulfonium salt compound and in particular relates to triaryl sulfonium salt containing 1-methyl-2-phenyl indole skeleton as well as a preparation method and application thereof. The preparation method of the triaryl sulfonium salt containing 1-methyl-2-phenyl indole skeleton comprises that 1-methyl-2-phenyl indole is taken as a raw material, diphenyl disulfide is taken as a sulfur source, a C-S bond coupling reaction is carried out for synthesizing aromatic sulfide, then a reaction is carried out on the aromatic sulfide and diaryl iodonium salt under the copper-catalyzed condition, so that the triaryl sulfonium salt containing 1-methyl-2-phenyl indole skeleton is obtained. Ultraviolet absorption wavelength of the triaryl sulfonium salt containing 1-methyl-2-phenyl indole skeleton can be more than 290nm in a red shift manner, the triaryl sulfonium salt containing 1-methyl-2-phenyl indole skeleton can be applied to an ultraviolet curing composition, especially ultraviolet curing coating, as a positive ion photoinitiator and has good reaction activity, surface curability and solubility, and the special group, namely 1-methyl-2-phenyl indole, is introduced, so that photo-initiation performance of the triaryl sulfonium salt containing 1-methyl-2-phenyl indole skeleton is effectively improved.

A syrup composition of the present invention comprises a mixture of monomers (A), each having a molecular mass of 130 to 300 and one (meth)acryloyl group; a resin (C) which is soluble in the monomers (A) and has a glass transition temperature of 20 to 155° C.; a wax (D); and a tertiary amine (E), wherein the monomers (A) contain a heterocyclic ring-containing (meth)acrylate (a1), an oligoethylene glycol monoalkyl ether (meth)acrylate (a2), and a hydroxyalkyl (meth)acrylate (a3) having a hydroxyalkyl group with 2 or 3 carbon atoms. The syrup composition does not substantially contain a polyvalent metal soap.

The invention discloses a photopolymerization monomer containing an active amine structure, and relates to the field of polymer material synthesis. The photopolymerization monomer is proposed based onthe problem that an initiator in an existing photocuring system is easy to migrate from a cured coating, and the photopolymerization monomer has the following chemical structural formula: (as described in the specification). The invention also discloses a preparation method of the photopolymerization monomer, which comprises the following steps: (1) reaction of glycidyl methacrylate and acrylic acid in the presence of a catalyst and a polymerization inhibitor; (2) dripping of secondary amine; and (3) purification of reaction products. The preparation method provided by the invention has the following beneficial effects: the reaction process is simple, the process conditions are easy to control, and an amine structure is introduced into a polymerization system, so that certain oxygen resistance and polymerization inhibition performance can be obtained, thereby obtaining better surface curing performance, avoiding migration of small molecular compounds, and preventing adverse effects onthe photocuring system.

The present invention provides an ultraviolet curing type cation electrodeposition coating composition which has advantages of excellent liquid aging stability, high sensitivity, excellent surface curability, excellent adhering property, excellent corrosion resistance, excellent wearing resistance and excellent medicine resistance. The ultraviolet curing type cation electrodeposition coating composition comprises the following compositions: A: 50-80 parts of water-soluble or water-dispersion vinyl copolymer which is obtained through the copolymerization of components a to c and is provided with unsaturated group at the end of one part of principal chain, and the components a-c are described as follows: a: 4-15 parts of copolymerized vinyl monomer which has t-aminoalkyl, b: 85-96 parts of copolymerized vinyl monomer except for a, and c: 0.05-20 parts of addition cracking chain transfer agent relatively to total 100 parts of a and b, B: 20-50 parts of composition with more than three unsaturated groups in one molecule; and C: a photopolymerization initiating agent which has a dissolving amount lower than 0.02g to 100g of water containing 3% of alcohol dissolvent and has a molar absorptivity of maxium absorption of 10 in 200nm to 400nm, wherein 0.1-8 parts of photopolymerization initiating agent exist relatively to total 100 parts of a and b.

The invention discloses hydroxyl-terminated polyurethane methacrylic resin as well as a preparation method and an application thereof; the structural general formula of the hydroxyl-terminated polyurethane methacrylic resin is represented by a formula 1, and the preparation method comprises the steps: carrying out copolymerization reaction on a hydroxyl acrylate body, and carrying out addition reaction and substitution reaction under catalytic conditions to obtain the hydroxyl-terminated polyurethane methacrylic resin. A hydroxyl-terminated polyurethane methacrylic resin base liquid is prepared from the prepared hydroxyl-terminated polyurethane methacrylic resin, a (methyl) acrylate monomer, an accelerant and a drying aid, and then an initiator is added to prepare a hydroxyl-terminated polyurethane methacrylic resin waterproof coating. The hydroxyl-terminated polyurethane methacrylic resin has the advantages that the low-temperature brittleness is reduced, the high-temperature flexibility is improved; hydroxyl is adopted for terminating and double bonds with activity are introduced, so the curing performance of the resin is enhanced, and the hydroxyl-terminated polyurethane methacrylic resin has great application and popularization value in the aspects of waterproof coatings and bonding materials.

An object of the present invention is to provide a dental composition with less change of color tone before and after curing and less color change after curing, and also with excellent thin-layer surface curability.Disclosed is a dental composition comprising 0.01 to 10 parts by weight of at least one kind of (a) a visible light.-photopolymerization catalyst compound and one or more kinds of (b) di(meth)acrylate compounds represented by the general formula (I):wherein R1 and R2 each independently represent hydrogen or a methyl group, and a repeating unit number n of an ethylene oxide group is from 9 to 50.

The invention relates to an amine co-initiator and a preparation method and application thereof. The structure of the amine co-initiator comprises amido and a triazine ring structure, the amine co-initiator is mixed with a hydrogen abstracting type photoinitiator for use, the curing rate can be effectively increased, yellowing after curing is relieved, oxygen inhibition is inhibited, and then the application effect of the amine co-initiator is improved; compared with EHA and EDB adopted by a traditional light curing system, the amine co-initiator has the advantages that the curing rate is obviously increased, and the curing effect is obviously improved; and the use amount of the amine co-initiator in a photocuring composition is small, and the cost is low.

The inventoin provides a colored photosensitive resin composition, a color filter, and an image display device. The colored photosensitive resin composition includes a mercaptan acrylate photo-polymerizable compound represented as the chemical formula (1), wherein the R1 groups are same as or independent from each other, each R1 being a straight-chain or branched-chain alkylene group having 2-40 carbon atoms and more than one oxygen atom; R1 is hydrogen or methyl group, n is an integer from 1 to 20; the content of the mercaptan acrylate photo-polymerizable compound is 10-30 weight parts when the total weight of the solid components in the colored photosensitive resin composition is 100 parts.

The invention relates to the field of ink and particularly relates to water-resistant, scratch-resistant and ultraviolet-cured ink for glass. The water-resistant, scratch-resistant and ultraviolet-cured ink for glass is prepared from the following raw materials in percentage by mass: 30-45% of mixture of aliphatic polyurethane acrylate oligomer and carboxylic acid modified polyester acrylate, 5-12% of initiator, 1-3% of surface auxiliaries, 5-10% of cosolvent, 10-20% of activated thinner, 1-2% of nano-silver antibacterial agent and 10-30% of inert solvent. The water-resistant, scratch-resistant and ultraviolet-cured ink has an antibacterial function while having good water resistance and scratch resistance, meanwhile, cannot affect the performance indexes of a coating material, and has relatively high salt mist resistance, aging resistance, adhesive power and cold / hot impact resistance.

A photocurable composition for a nail or artificial nail which can form a cured product exhibiting excellent durability (adhesion maintainability to nails). In addition, the present invention provides a photocurable composition for a nail or artificial nail which emits a weaker odor, generates less heat at the time of curing, and can form a cured product exhibiting excellent surface curability. In addition, the present invention provides a photocurable composition for nail or artificial nail which can form a cured product having an excellent shear adhesive force. The photocurable composition for nail or artificial nail according to the present invention contains the following components (A) to (D): component (A): a urethane-modified (meth)acrylic oligomer; component (B): a (meth)acrylamide monomer; component (C): a (meth)acrylic monomer having an acidic group; and component (D): a photoinitiator.

The invention discloses a phenyl benzothiophene ketone compound and a preparation method thereof. According to the method, benzothiophene used as a raw material is subjected to acylation to ensure that benzoyl is introduced a thiophene ring so as to prepare the phenyl benzothiophene ketone compound; the ultraviolet absorption wavelength of the compound can be shifted to the wavelength of 319nm; and due to the presence of the thiophene ring, the range of the ultraviolet absorption wavelength can be widened. The prepared phenyl benzothiophene ketone compound serving as a photoinitiator is used for an ultraviolet light cured composite, particularly ultraviolet light cured coating, and is high in reactivity, surface curing capacity and dissolubility; a molecule has a benzothiophene structure,so that the molecule is relatively stable; and therefore, the release amount of benzene is effectively reduced.

A method for ultraviolet curing an adhesive layer in a thermal transfer film is disclosed. The method includes the following steps: sticking the adhesive layer on a surface of printing stock through heating and pressurizing; peeling a carrier layer in the thermal transfer film to transfer an image layer in the thermal transfer film onto the surface of printing stock; and further curing the adhesive layer by subjecting to an ultraviolet radiation. The adhesive layer comprises prepolymer, reactive diluents, resin, curing agent and additives. The curing agent comprises cationic photoinitiator and free-radical photoinitiator. This method has the advantage of good curing effect, improved adhesive performance, lower curing shrinkage rate and excellent image surface smoothness.

The invention discloses a UV-curable silicone release agent. The release agent has good storage stability at room temperature, and it will not be moisture-cured when exposed to the air, but UV light can quickly trigger moisture curing and UV curing. It belongs to the UV / moisture dual curing system, which is different from ordinary UV / Moisture dual-cure systems are different in that moisture curing is initiated only after UV exposure. The specific composition is (meth)acryloyloxyalkylureido double-capped polydimethylsiloxane, mercapto silicone oil, organotin catalyst capable of forming a complex with mercapto silicone oil, and a photoinitiator. Compared with ordinary UV-curable silicone, the release agent of the invention is beneficial to eliminate the polymerization inhibition effect of oxygen on the surface of the silicone, improve the surface curability of the silicone, and the cured product has a good release effect.

The utility model relates to the field of ink, in particular to an ultraviolet curing screen printing ink for an acrylic decorative plate. The ultraviolet-curing screen printing ink is characterized by being prepared from the following raw materials in percentage by mass: 30-45 percent of the mixture of polyurethane diacrylate and epoxy acrylate, 3-5 percent of pentaerythritol triacrylate, 5-12 percent of an initiator, 1-3 percent of a surface additive, 5-10 percent of a co-solvent, 10-20 percent of a reactive diluent, 1-2 percent of polyacrylate or an organosilicon leveling agent, 10-30 percent of an inert solvent and 1-2 percent of pigment. The ultraviolet curing screen printing ink is high in toughness, tensibility and glossiness and further is relatively high in aging resistance, abrasion resistance, scratching resistance, adhesive force, and hot and cold impact resistance.