The invention discloses low-
aldehyde and low-
odor polyether
polyol as well as a preparation method and application thereof, the polyether
polyol is prepared by adopting a
phosphazene catalyst and carrying out
polymerization reaction on an active
hydrogen compound and oxyalkylene, and the molecular weight is 800-15000; the functionality is 2-6; the
formaldehyde content is less than or equal to 0.01 ppm, the
acetaldehyde content is less than or equal to 0.01 ppm, the
acrolein content is less than or equal to 0.01 ppm, the
propionaldehyde content is less than or equal to 0.01 ppm, and the
odor grade is less than or The catalyst is prepared by dissolving
phosphorus pentahalide in a non-
benzene organic solution, reacting with a
guanidine compound to obtain an organic
phosphonium salt solution, mixing and reacting with an
alkali metal salt compound, filtering,
drying, performing reduced pressure
distillation and purifying. The
polyol can be used for preparing a low-
odor polyurethane material. The specific
phosphazene catalyst is adopted for
polymerization reaction, the content of by-products generated due to
chain transfer is effectively reduced, and the prepared polyether polyol is low
in degree of unsaturation, low in
aldehyde content and low in odor.