The invention discloses a solidification and stabilization method for a hazardous waste containing toxic organic compounds, which belongs to the hazardous waste treatment technical field of environment protection. According to a dry weight ratio, 30 to 60 percent of the hazardous waste containing toxic organic compounds, 0.5 to 10 percent of an additive, 30 to 60 percent of inorganic cementing agent and curing agent are added into an agitator and are stirred by adding water, meanwhile, a gas internal circulation device is started, the gas in the agitator is adsorbed and purified by a gas adsorbing and purifying device, and then part of the gas is fed back into the agitator; after being evenly mixed and stirred materials are discharged, solidified and fed into a maintenance house, and the solidification and stabilization of the hazardous waste containing toxic organic compounds is finished. The additive comprises an adsorbent with adsorbing effect and a structural modifier which can improve the structural performance of a product, such as activated carbon, water glass, calcium chloride, etc. The inorganic cementing agent and curing agent refers to hydraulicity cementing material. The solidification rate of the invention can reach more than 90 percent; and gas circulation can reduce polluted gas discharging, thus being capable of effectively reducing the occurrence of secondary pollution.