Compared with the prior art, the acid-resistant glass fiber composition provided by the invention has the advantages that the content ranges of four main components, namely SiO2, Al2O3, Na2O and CaO,are accurately regulated and controlled, so that the internal structure of the glass fiber is optimized, and the glass fiber is ensured to have good mechanical property, corrosion resistance and forming property, and the problem that the high-performance glass fiber is difficult to obtain under the condition of low production difficulty is solved. Meanwhile, a proper amount of K2O, MgO, ZrO, B2O3and Fe2O3 components are properly introduced, so that the forming operation of the glass fiber is further improved, the forming operation difficulty is reduced, and the mechanical property and the corrosion resistance, especially the acid resistance, of the glass fiber are improved; In addition, the obtained glass fiber does not contain boron, fluorine and harmful clarifying agents, so that the service life of the refractory material of the kiln is prolonged, energy conservation, environmental protection and emission reduction are realized, and the glass fiber is easy to realize industrial production.