The invention discloses an electric drive axle structure with double motors and a working method of the electric drive axle structure, and belongs to the technical field of automobile transmission systems. The structure comprises a first motor, a second motor, an epicyclic gear train, a driving gear, a driven gear, a differential mechanism, a driving half shaft and a brake. The first motor stator, the first motor rotor, the second motor stator and the second motor rotor are all arranged on the shaft; the epicyclic gear train comprises a gear ring, a planet carrier, a sun gear and a planet gear; the first motor rotor is fixedly connected with the sun gear, the second motor rotor is fixedly connected with the gear ring, and the gear ring is connected with the brake; one side of the planet carrier is connected with the planet wheel, the other side of the planet carrier is connected with the driving gear, the driving gear is meshed with the driven gear, and the driven gear is connected with the differential mechanism which is connected with the driving half shaft. The invention is compact in structure, high in flexibility, easy to install and maintain and capable of being suitable for different operation working conditions, and the cruising ability of the vehicle is effectively improved.