The invention discloses a low-temperature sintered V series ZnO voltage-sensitive ceramic material and a preparation method thereof, and belongs to the technical field of functional ceramic preparation and application. The low-temperature sintered V series ZnO voltage-sensitive ceramic material uses ZnO-V2O5 as a matrix, and oxides of Mn, Nb, Gd and Er as modified additives. The preparation method includes mixing, ball milling, drying, granulation, sieving, molding for forming, sintering and silver electrode preparation. The V1mA of ZnO pressure-sensitive ceramic material obtained by the invention has varistor voltage from 200 to 400 V / mm, nonlinear coefficient alpha greater than 20, and leakage current IL of 0.10- 0.35 mA; and the sintering temperature is 800 to 950 DEG C. compared to the Bi series and Pr series ZnO voltage-sensitive ceramic materials, the V series ZnO voltage-sensitive material provided by the invention has greatly reduced sintering temperature, good comprehensive performance, and simple preparation process, safety and reliability, and is expected to realize low temperature co-firing of MLV ceramic layer voltage-sensitive material with a silver electrode.