The invention discloses a
fullerene single
catechol derivative intermediate, a preparation method thereof and purposes thereof. The preparation method is characterized in that 0.3-14 parts of 3,4-dibenzyloxybenzoic acid are dissolved in 2-10 parts of
tetrahydrofuran at -15--18 DEG C, 0.01-1 part of
triethylamine is added in the solution, 0.09-1 part of
ethyl chloroformate is dripped in the reactor, the solution is stirred for 2-3 hours,
triethylamine hydrochloride is removed through filtering, THF is removed in a pressure reducing mode, 0.1-4.0 parts of
fullerene ethylenediamine derivatives intermediates IV, and 16-100 parts of methylbenzene are added in the solution and react at 140-150 DEG C, TLC is used for detecting reaction progresses, the methylbenzene is removed after
filtration and
pressure reduction, 1-10 parts of
dichloromethane are added and dissolved in the solution, 6-7 parts of saturated
salt water is used for washing for three times, 10-12 parts of saturated
sodium bicarbonate are sued for washing for five times,
anhydrous sodium sulfate is used for washing organic phases, the
column chromatography developing
solvent includes
dichloromethane and
ethyl acetate with a ratio of 20:1, and 0.05-2.5 parts of
fullerene single
catechol derivatives intermediates V are obtained. The productive rate is 30.6%-38.8%.