The invention discloses a composite glass clarifying agent, which belongs to the field of the glass production. The composite glass clarifying agent is prepared from the raw materials such as acrylamide and sodium dimethyl diacrylamide sulfonate and can be slowly expanded after being heated, and can form a wrapping and supporting effect for a netted structure formed by silicate and SiO2 in a glasssystem, polymer microspheres comprise partial gas in the preparation process, in the application process, the partial gas overflows rapidly, so that the dispersity is good, and a better bubble inhibition and removal effect can be achieved; and polyether is introduced into the organic silicon, no only can the hydrophilic group but also the oleophylic group be provided, by introducing the paraffinand microcrystalline paraffin, a long-chain aliphatic compound can be introduced, the silicon tetrahydride can be rapidly hydrolyzed into orthosilicic acid and hydrogen under an alkaline condition, generation of other bubbles can be prevented, the secondary bubbles can be further prevented, and a better bubble eliminating effect can be achieved. By adopting the composite glass clarifying agent, the problem that the conventional glass clarifying agent is poor in bubble removal efficiency.