A 
system for characterizing the electrical properties of 
semiconductor wafers with 
high surface state densities, such as GaN wafers, includes a support subsystem for supporting the 
semiconductor sample, at least one 
light source for illuminating a spot on the sample, and a detection subsystem for measuring the photovoltage 
signal produced from illumination of the sample. In use, the 
system utilizes in-line, non-contact photovoltage techniques that exploits the presence of the 
high surface state density and the known components of its associated electrostatic barrier as part of its novel characterization process. Specifically, the 
system illuminates the sample with one or more light beams that vary in 
photon energy and duration in order to excite charge carriers in specific 
layers of the sample while either preserving or collapsing the electrostatic barrier. In this manner, the system is able to electrically characterize individual or combined 
layers of the sample as well as embedded junctions.