The invention discloses a processing method for enhancing fluffiness of white duck down. The method includes the following steps: mixing ferric chloride hexahydrate, ferrous sulfate heptahydrate and water, heating and stirring, adding ammonia water, stirring uniformly, adding humic acid and whey protein, stirring continuously, adding mercaptoethanol, stirring continuously, removing mercaptoethanol, cooling, filtering, washing to neutrality, and drying the mixture to obtain prefabricated materials; washing white duck down, drying, adding the prefabricated materials, coconut oil hydroxyethyl sodium sulfonate, laurel essential oil, sodium dodecyl sulfate and water, uniformly mixing, dipping, filtering and washing the mixture to obtain pretreated white duck down; and drying the pretreated white duck down, spraying a down finishing agent in the drying process, and sterilizing to obtain the white duck down with high fluffiness.