The invention relates to a pure natural shampoo prepared from Chinese herbal medicine raw materials. The pure natural shampoo is prepared from the processed Chinese herbal medicine raw materials in parts by weight: 25-30 parts of sesame seeds, 15-20 parts of peach kernels, 20-25 parts of angelica sinensis, 25-30 parts of radix polygonum multiflorum preparata, 20-25 parts of cacumen platycladi, 5-7 parts of apricot kernels, 5-7 parts of flos chrysanthemi indici, 5-7 parts of radix sileris, 5-7 parts of common ducksmeat herb, 15-18 parts of herba ecliptae, 15-18 parts of fructus ligustri lucidi, 10-12 parts of ligusticum wallichii, 10-15 parts of taraxacum officinale and 5-7 parts of liquorice. The pure natural shampoo disclosed by the invention is mainly used for people with scalp diseases, such as dandruff, hair oiliness, hair wilt, leukotrichia, alopecia areata, alopecia, intermittent headache and scale macules, is safe, nontoxic and obvious in effect after being used, can also be used for common people without the scalp diseases and has the beneficial effects of hair helpfulness and hairdressing, such as head clarity, scalp relax and hair glossiness, nourishing and smoothness.