The invention relates to a solar-energy low-temperature thermal power-generation and photovoltaic power-generation combination system, comprising a compound parabolic collector system, a heat storage system, an organic rankine cycle power-generation system, a photovoltaic module and a photovoltaic power-supply system, wherein the compound parabolic collector system comprises a high-temperature end compound parabolic collector array and a low-temperature end compound parabolic collector array, and the photovoltaic module is arranged on the upper part of a heat absorber of the compound parabolic collector; the heat storage system comprises a liquid storage tank in which coil pipes are equally arranged, and PCM (phase change material) is filled in the coil pipes; the organic rankine cycle power-generation system comprises an evaporator, a steam turbine, a generator, a heat regenerator, a condenser, two pumps and six valves. The total power-generation efficiency of the combination system is greatly enhanced; and the adoption of the heat storage system avoids the application of additional accumulators and complicated tracking devices, thus reducing cost; and the adoption of two-class evaporator reduces non-reversibility of heat transmission of heat-exchanging fluid and organic work-medium so as to reduce average running temperature, thus being in favor of prolonging service life of photovoltaic cells.