The present invention relates to environment friendly microwave dielectric ceramic for dielectric resonator, filter, vibrator and other microwave elements and devices in Ku band satellite communication system. The microwave dielectric ceramic contains ZrO2, SnO2 and TiO2 as well as micro additives ZnO, La2O3, Co2O3, CuO, SiO2, etc. It is prepared through mixing the materials, ball milling, calcining, crushing, pelletizing, forming, sintering and other steps. It features the low sintering temperature resulting in low power consumption, medium dielectric constant, high quality factor and temperature stable resonant frequency.