The invention discloses a geopolymer cementing material for pavement base based on multielement solid waste synergy and a preparation method of the geopolymer cementing material. The geopolymer cementing material is mainly characterized in that fly ash, slag, carbide slag and desulfurized gypsum are used as main materials, the characteristics of various solid wastes are fully played, and the geopolymer cementing material is prepared on the basis of the principle of the geopolymer cementing material by utilizing the synergistic enhancement effect of the solid wastes. Through three main procedures of drying, grinding and secondary uniform mixing, the geopolymer cementing material special for the pavement base is prepared, wherein various performance indexes of the geopolymer cementing material meet the requirements of JT/T 994-2015 Cement for Highway Engineering Pavement Base Stability. Compared with the traditional cement-stabilized pavement base material, the dry shrinkage of the cement-stabilized pavement base material is greatly improved, and the crack hazard of the pavement caused by the dry shrinkage of the base is obviously reduced. Meanwhile, a large number of road building materials can be saved, waste is fully utilized, energy is saved, environmental pollution is reduced, resources are saved, the environment is protected, the road quality is improved, and the green traffic development concept is met.